Theory of the chemical bond. V. Bond polarities of posttransition hydrides

Robert L. Matcha; Stephen C. King; B. M. Pettitt

doi:10.1063/1.440580

Theory of the chemical bond. V. Bond polarities of posttransition hydrides

Robert L. Matcha, Stephen C. King, B. M. Pettitt

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

A classical derivation of a dipole moment model derived earlier by a quantum mechanical implicit perturbation technique is given. This model is used to determine the bond polarities of the posttransition (Groups IIIA-VIIA) hydrides. The polarity measures the extent of charge transfer in a bond. Polarities of alkali halides and posttransition hydrides are used to illustrate the gradual change in bond polarities with nuclear charge across the periodic table.

Original language	English (US)
Pages (from-to)	3944-3946
Number of pages	3
Journal	The Journal of chemical physics
Volume	73
Issue number	8
DOIs	https://doi.org/10.1063/1.440580
State	Published - 1980
Externally published	Yes

ASJC Scopus subject areas

General Physics and Astronomy
Physical and Theoretical Chemistry

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10.1063/1.440580

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abstract = "A classical derivation of a dipole moment model derived earlier by a quantum mechanical implicit perturbation technique is given. This model is used to determine the bond polarities of the posttransition (Groups IIIA-VIIA) hydrides. The polarity measures the extent of charge transfer in a bond. Polarities of alkali halides and posttransition hydrides are used to illustrate the gradual change in bond polarities with nuclear charge across the periodic table.",

author = "Matcha, {Robert L.} and King, {Stephen C.} and Pettitt, {B. M.}",

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AB - A classical derivation of a dipole moment model derived earlier by a quantum mechanical implicit perturbation technique is given. This model is used to determine the bond polarities of the posttransition (Groups IIIA-VIIA) hydrides. The polarity measures the extent of charge transfer in a bond. Polarities of alkali halides and posttransition hydrides are used to illustrate the gradual change in bond polarities with nuclear charge across the periodic table.

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Theory of the chemical bond. V. Bond polarities of posttransition hydrides

Abstract

ASJC Scopus subject areas

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