Abstract
We examine a light-driven dissipative engine, which must necessarily operate far from equilibrium and at a nonzero rate to be capable of providing power and work. The engine's working fluid consists of a buffer gas and the reacting system 2SO3F⇄S2O6F2. We model the concentrations of the reacting system as functions of both temperature and pressure. Piston trajectories maximizing work output and minimizing entropy production are determined for such an engine with the rate-dependent loss mechanisms of friction and heat conduction.
Original language | English (US) |
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Pages (from-to) | 131-147 |
Number of pages | 17 |
Journal | Il Nuovo Cimento B |
Volume | 104 |
Issue number | 2 |
DOIs | |
State | Published - Aug 1989 |
Externally published | Yes |
Keywords
- Nonequilibrium thermodynamics
- Other topics in physical chemistry
- PACS 05.70.Ln
- PACS 44.60
- PACS 82.90
- Thermodynamic processes (phenomenology, experimental techniques)
- irreversible processes
ASJC Scopus subject areas
- General Physics and Astronomy